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Physics Maths Engineering

Boron Recovery from Organic Solutions Used in Brine Treatment through a Water Stream

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Alejandra Cerda,

Alejandra Cerda

Departamento de Ingeniería Química y Procesos de Minerales, Facultad de Ingeniería, Universidad de Antofagasta, Av. Angamos 601, Antofagasta 1240000, Chile


Mackarena Jara,

Mackarena Jara

SQM, El Trovador 4285, Santiago 7550000, Chile


Osvaldo Yañez,

Osvaldo Yañez

SQM, El Trovador 4285, Santiago 7550000, Chile


Yahaira Barrueto,

Yahaira Barrueto

Departamento de Ingeniería Metalúrgica y Materiales, Universidad Técnica Federico Santa María, Valparaíso 2340000, Chile


Yecid P. Jimenez

Yecid P. Jimenez

Departamento de Ingeniería Química y Procesos de Minerales, Facultad de Ingeniería, Universidad de Antofagasta, Av. Angamos 601, Antofagasta 1240000, Chile


  Peer Reviewed

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© attribution CC-BY

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rating
429 Views

Added on

2024-12-01

Doi: http://dx.doi.org/10.3390/min14030265

Related Subjects
Physics
Math
Chemistry
Computer science
Engineering
Earth science
Biology

Abstract

Abstract

This research evaluates the modification of the lithium carbonate (Li2CO3) production process and particularly the boron removal step, which currently employs a recirculated stream. This recirculated stream is a liquor with low boron content but rich in lithium, currently being wasted. In this process, the recirculating stream is substituted with a freshwater stream. Boron is re-extracted from the loaded organic stream to form an input stream for a boric acid process. Under certain operational conditions, the formation of emulsions was observed; due to this, the analysis of emulsion formation involved controlling the pH of each sample, which lead to the development of a procedure to prevent such formations. From this analysis, it was determined that emulsions form in water with pH values below 1.3 and above 6.9. In addition, a speciation analysis showed that the concentrations of the H2BO3− and H+ species influence the formation of emulsions. The mass balance of the process showed that by replacing the recirculated stream, boron recovery of 89% was achieved, without the need to add new stages or equipment.

Key Questions

How do you remove boron from brine?

Boron can be removed from brine by acidifying it to pH 0.1-6.0 and contacting it with an organic extraction medium containing diols with 6-20 carbon atoms.

What are the best solvents for extracting boron?

Effective solvents for boron extraction include 2-ethyl-1,3-hexane diol, isopentanol, isooctyl alcohol, and isodecanol dissolved in aromatic or kerosene solvents.

How efficient is reverse osmosis for boron removal?

Reverse osmosis can remove up to 50% of boron under neutral conditions and nearly 100% under alkaline conditions.

What factors affect boron removal by reverse osmosis?

Key factors include solution pH, initial boron concentration, salinity, temperature, recovery ratio, pressure, and feed flow rate.

How does pH affect boron removal?

Increasing pH generally improves boron removal efficiency for most processes, including reverse osmosis, forward osmosis, and solvent extraction.

What is the best way to recover boron from salt lake brines?

Solvent extraction using monohydric alcohols like isodecanol can achieve over 99% boron recovery from salt lake brines with high magnesium content.


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Article usage: Dec-2024 to May-2025
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2025 May 114 114
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2024 December 61 61
Total 429 429
Show by month Manuscript Video Summary
2025 May 114 114
2025 April 80 80
2025 March 63 63
2025 February 53 53
2025 January 58 58
2024 December 61 61
Total 429 429
Related Subjects
Physics
Math
Chemistry
Computer science
Engineering
Earth science
Biology
copyright icon

© attribution CC-BY

  • 0

rating
429 Views

Added on

2024-12-01

Doi: http://dx.doi.org/10.3390/min14030265

Related Subjects
Physics
Math
Chemistry
Computer science
Engineering
Earth science
Biology

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