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Sambasivarao Kotha,
Sambasivarao Kotha
Department of Chemistry, Indian Institute of Technology, Bombay 400076, India
Subba Rao Cheekatla
Subba Rao Cheekatla
Department of Chemistry, Indian Institute of Technology, Bombay 400076, India
Herein, we report a bisoxazole derivative as well as a bromo-substituted oxazole derivatives via a simple approach. The synthesis begins with an inexpensive and readily available starting material, such as 2,5-dimethoxybenzaldehyde, hydroquinone, and p-toluenesulfonylmethyl isocyanide (TosMIC). This approach relies on the Van Leusen oxazole method and electrophilic aromatic bromination. Th...
5 months ago
Ridho Asra,
Ridho Asra
School of Pharmacy, Institute of Clinical Sciences, College of Medical and Dental Sciences, University of Birmingham, Birmingham B15 2TT, UK
Aigul Erbosynovna Malmakova,
Aigul Erbosynovna Malmakova
School of Pharmacy, Institute of Clinical Sciences, College of Medical and Dental Sciences, University of Birmingham, Birmingham B15 2TT, UK
Alan M. Jones
Alan M. Jones
School of Pharmacy, Institute of Clinical Sciences, College of Medical and Dental Sciences, University of Birmingham, Birmingham B15 2TT, UK
Abstract
The tractable preparation of Phase I drug metabolites is a critical step to understand the first-pass behaviour of novel chemical entities (NCEs) in drug discovery. In this study, we have developed a structure–electroactivity relationship (SeAR)-informed electrochemical reaction of the parent 2-chlorophenothiazine and the ...
5 months ago
Summary
This study examines the relationship between carbon emissions and low-carbon innovation in firms using panel data from Chinese A-share listed companies from 2010 to 2019. The key findings include:
- Carbon emissions promote low-carbon innovation in firms
- This effect is mediated by carbon emissions reduction pressure...
5 months ago
Krystal M. Cid-Seara,
Krystal M. Cid-Seara
Departamento de Química Inorgánica, Universidade de Vigo, Campus Universitario, 36310 Vigo, Spain
Raquel Pereira-Cameselle,
Raquel Pereira-Cameselle
Departamento de Química Orgánica, Universidade de Vigo, Campus Universitario, 36310 Vigo, Spain
Sandra Bolaño,
Sandra Bolaño
Departamento de Química Inorgánica, Universidade de Vigo, Campus Universitario, 36310 Vigo, Spain
Maria Talavera
Maria Talavera
Departamento de Química Inorgánica, Universidade de Vigo, Campus Universitario, 36310 Vigo, Spain
Organic amines are important compounds present in a wide variety of products, which makes the development of new systems for their detection an interesting field of study. New organometallic complexes of group 9 [MCp*X(2′-R-2-py-SBF)] (M = Ir, Rh; R = H, X = Cl (6), R = H, X = OAc (7), R = CHO, X = Cl (8)), and [IrCp*Cl(2′, 7-diCHO-2-py-SBF)] (9) (Cp* pentamethylcyclopentadienyl, SBF =...
6 months ago
Omar Ali Shaban Al-Awad,
Omar Ali Shaban Al-Awad
School of Agriculture and Environment, University of Western Australia, 35 Stirling Highway, Perth, WA 6009, Australia
Kit Stasia Prendergast,
Kit Stasia Prendergast
School of Molecular and Life Sciences, Curtin University, Kent Street, Bentley, Perth, WA 6102, Australia
Alan Robson,
Alan Robson
School of Agriculture and Environment, University of Western Australia, 35 Stirling Highway, Perth, WA 6009, Australia
Zed Rengel
Zed Rengel
School of Agriculture and Environment, University of Western Australia, 35 Stirling Highway, Perth, WA 6009, Australia
Soil ammonium toxicity can decrease plant growth, and many crop species have low resistance to ammonium, including canola, an economically important crop. Different genotypes may differ in their resistance to ammonium toxicity, and therefore determining if there are genotypes that exhibit variation in their ability to tolerate soil ammonium is a research priority. Here, we evaluate how soi...
7 months ago
Elain Fu,
Elain Fu
School of Chemical, Biological and Environmental Engineering, Oregon State University, Corvallis, OR 97331, USA
Khadijeh Khederlou,
Khadijeh Khederlou
School of Chemical, Biological and Environmental Engineering, Oregon State University, Corvallis, OR 97331, USA
Noël Lefevre,
Noël Lefevre
School of Chemical, Biological and Environmental Engineering, Oregon State University, Corvallis, OR 97331, USA
Stephen A. Ramsey,
Stephen A. Ramsey
School of Electrical Engineering and Computer Science, Oregon State University, Corvallis, OR 97331, USA
Matthew L. Johnston,
Matthew L. Johnston
School of Electrical Engineering and Computer Science, Oregon State University, Corvallis, OR 97331, USA
Lael Wentland
Lael Wentland
School of Chemical, Biological and Environmental Engineering, Oregon State University, Corvallis, OR 97331, USA
Electrochemical detection, with its advantages of being rapid, multi-time point, compatible with cost-effective fabrication methods, and having the potential for miniaturization and portability, has great promise for point-of-care drug monitoring. However, a continuing challenge concerns the robust and sensitive electrochemical detection of pharmaceutical analytes from biological fluids. T...
7 months ago
Mònica Campàs,
Mònica Campàs
IRTA, Marine and Continental Waters (AMiC) Programme, Ctra. Poble Nou del Delta, km. 5.5, 43540 La Ràpita, Spain
Jaume Reverté,
Jaume Reverté
IRTA, Marine and Continental Waters (AMiC) Programme, Ctra. Poble Nou del Delta, km. 5.5, 43540 La Ràpita, Spain
Àngels Tudó,
Àngels Tudó
Department of Basic Medical Sciences, Universitat Rovira i Virgili, C/Sant Llorenç 21, 43201 Reus, Spain
Mounira Alkassar,
Mounira Alkassar
IRTA, Marine and Continental Waters (AMiC) Programme, Ctra. Poble Nou del Delta, km. 5.5, 43540 La Ràpita, Spain
Jorge Diogène,
Jorge Diogène
IRTA, Marine and Continental Waters (AMiC) Programme, Ctra. Poble Nou del Delta, km. 5.5, 43540 La Ràpita, Spain
Francesc X. Sureda
Francesc X. Sureda
Department of Basic Medical Sciences, Universitat Rovira i Virgili, C/Sant Llorenç 21, 43201 Reus, Spain
Tetrodotoxin (TTX) is a marine toxin responsible for many intoxications around the world. Its presence in some pufferfish species and, as recently reported, in shellfish, poses a serious health concern. Although TTX is not routinely monitored, there is a need for fast, sensitive, reliable, and simple methods for its detection and quantification. In this work, we describe the use of an auto...
7 months ago
James P. C. Coverdale,
James P. C. Coverdale
School of Pharmacy, Institute of Clinical Sciences, University of Birmingham, Edgbaston B15 2TT, UK
Sirilata Polepalli,
Sirilata Polepalli
Department of Chemistry, University of Warwick, Coventry CV4 7AL, UK
Marco A. Z. Arruda,
Marco A. Z. Arruda
Institute of Chemistry, Department of Analytical Chemistry, Universidade Estadual de Campinas, Campinas 13083-970, Brazil
Ana B. Santos da Silva,
Ana B. Santos da Silva
Institute of Chemistry, Department of Analytical Chemistry, Universidade Estadual de Campinas, Campinas 13083-970, Brazil
Alan J. Stewart,
Alan J. Stewart
School of Medicine, University of St. Andrews, St Andrews KY16 9TF, UK
Claudia A. Blindauer
Claudia A. Blindauer
Department of Chemistry, University of Warwick, Coventry CV4 7AL, UK
Interactions between proteins and metal ions and their complexes are important in many areas of the life sciences, including physiology, medicine, and toxicology. Despite the involvement of essential elements in all major processes necessary for sustaining life, metalloproteomes remain ill-defined. This is not only owing to the complexity of metalloproteomes, but also to the non-covalent c...
7 months ago
Zhongbo Liu,
Zhongbo Liu
Department of Urology, University of California Irvine, Orange, CA 92868, USA
Liankun Song,
Liankun Song
Department of Urology, University of California Irvine, Orange, CA 92868, USA
Jun Xie,
Jun Xie
Department of Urology, University of California Irvine, Orange, CA 92868, USA
Xue-Ru Wu,
Xue-Ru Wu
Department of Urology, NYU School of Medicine, New York, NY 10016, USA
Greg E. Gin,
Greg E. Gin
Department of Urology, University of California Irvine, Orange, CA 92868, USA
Beverly Wang,
Beverly Wang
Department of Pathology and Laboratory Medicine, University of California, Irvine, Orange, CA 92868, USA
Edward Uchio,
Edward Uchio
Department of Urology, University of California Irvine, Orange, CA 92868, USA
Xiaolin Zi
Xiaolin Zi
Department of Urology, University of California Irvine, Orange, CA 92868, USA
UPII-mutant Ha-ras transgenic mice develop urothelial hyperplasia and low-grade papillary carcinoma, which mimics human non-muscle invasive bladder cancer (NMIBC). We investigated the effects and mechanisms of kawain, a main kavalactone in the kava plant, on oncogenic Ha-ras-driven urothelial carcinoma in these mice. The mice were fed at six weeks of age with vehicle control or kawain (6 g...
7 months ago
The article gives a brief description of geroprotection and rejuvenation methods known to date, presenting their main mechanisms and limitations. To overcome the main limitations of the process of rejuvenation, it is possible to use a process called “cell autocloning.” The principle of the proposed method of rejuvenation is as follows: a periodic process of autocloning of the cell nucleus is i...
7 months ago